Hey Joseph!!! Hope you’re doing well, and thanks for your question.
[br]Typically, the bluesy sound comes from the mixing of both the major and minor third (notes) with a minor seventh - so this presents a bit of a grey area when trying to explain the theory.
[br]First, let’s spell out the notes in a dominant 7th chord: root, major third, fifth, and minor seventh. So right away, we’ve got a note from the major scale mixed with a note from the minor scale.
[br]When we play over a blues progression that uses dominant chords, it sounds good and “bluesy” to mix the major and minor 3rds. A usual example is when we put a bluesy bend on the minor 3rd note - we are bending it up to the major 3rd. This is just one of the hallmarks of the sound of the blues. The minor pentatonic scale gets us that “built in” sound, and we can either bend up to the major third note, or simply add it to the scale. The minor pentatonic scale also contains a minor seventh note, so that works out nicely.
[br]Generally, it doesn’t sound as good to mix the major 7th in there, so you’re better to stick with the minor 7 (or b7) note.
[br]You could also use the “Blues Scale” which is the minor pentatonic with an added minor 5th (or b5) note. This also gives a very bluesy sound.
[br]As for using the major pentatonic over the dominant 7th chord progression - yes, you can do this!! It gives a slightly different sound - a bit brighter, but still bluesy. In fact, we often switch between using the minor and major pentatonic scales when improvising over a blues.
[br]In the case of a Minor Blues - which uses Im IVm and Vm chords -- you’d want to stick with minor pentatonic or the minor scale for it to sound right.
[br]I hope this helps!! Let me know how it goes!
Mike
Keep rockin!
Mike Olekshy
GT Guitar Coach